Remote functionalization of hydrocarbons with reversibility enhanced stereocontrol† †Electronic supplementary information (ESI) available: Experimental procedures, computational details, list of coordinates and energies (E, H and G) of optimized structures, spectroscopic data and copies of 1H and 13C NMR spectra. See DOI: 10.1039/c5sc00445d

Carborane-based design of a potent vitamin D receptor agonist† †Accession number. The coordinates and structure factors are deposited in the Protein Data Bank under the accession code 5E7V. ‡ ‡Electronic supplementary information (ESI) available: Experimental procedures, computational details, spectroscopic data and copies of 1H and 13C NMR spectra and characterization data for all new compounds. See DOI: 10.1039/c5sc03084f Click here for additional data file.

Departamento de Qúımica Orgánica, Lab Universidad de Santiago de Compostela, Compostela, Spain. E-mail: antonio.mourin Departamento de Fisioloǵıa–CIMUS, Unive 15706 Santiago de Compostela, Spain Department of Integrative Structural Biolo U964, 1, rue Laurent Fries, 67400 Illkirch, F Departmento de Qúımica Fundamental, Zapateira s/n, 15071 A Coruña, Spain † Accession number. The coordinates and ...

Gold(iii)–arene complexes by insertion of olefins into gold–aryl bonds† †Electronic supplementary information (ESI) available: Experimental details (syntheses, analytical data and copies of 1H, 13C and 31P NMR spectra), crystallographic data of 2 and computational details. CCDC 1526613 and 1538015. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c7sc00145b Click here for additional data file. Click here for additional data file.

Palladium-catalyzed ligand-promoted site-selective cyanomethylation of unactivated C(sp3)–H bonds with acetonitrile† †Electronic supplementary information (ESI) available: Experimental details including characterization data, copies of 1H, 13C NMR and NOESY spectra. See DOI: 10.1039/c5sc04066c Click here for additional data file.

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Copper-catalyzed direct alkylation of heteroarenes† †Electronic supplementary information (ESI) available: Experimental procedures, characterization and copies of 1H and 13C NMR spectra for all new compounds. See DOI: 10.1039/c6sc05622a Click here for additional data file.

8-Styryl-substituted coralyne derivatives as DNA binding fluorescent probes† †Electronic supplementary information (ESI) available: Experimental procedures, additional spectroscopic data, 1H and 13C NMR spectra of 2 and 4a–f. See DOI: 10.1039/c6ra27684a Click here for additional data file.